This paper gives a comprehensive review on the recent progress in solid-state electrolyte materials for sodium-ion battery, including inorganic ceramic/glass-ceramic, organic polymer and ceramic-polymer composite electrolytes, and also provides a comparison of the ionic conductivity in various solid-state electrolyte materials.
However, the commercial development and large-scale application of solid-state sodium-ion batteries urgently need to address issues such as the low room-temperature ionic conductivity of solid electrolytes, high interfacial charge transfer impedance, and poor compatibility and contact between the solid electrolytes and the electrodes.
Finally, the future industrial development of sodium-ion solid-state batteries is prospected. Sodium-ion batteries have abundant sources of raw materials, uniform geographical distribution, and low cost, and it is considered an important substitute for lithium-ion batteries.
A trend of publication numbers for solid electrolytes of sodium-ion batteries in recent years. (Note datas from Web of Science on 21/09/2022) Different research groups have highlighted the following characteristics of SSE: electrochemical stability, mechanical strength, and increased energy density [68, 69, 70].
All-solid-state sodium ion batteries (AS 3 iBs) are highly sought after for stationary energy storage systems due to their suitable safety and stability over a wide temperature range. Hard carbon (HC), which is low cost, exhibits a low redox potential, and a high capacity, is integral to achieve a practical large-scale sodium-ion battery.
All-solid-state sodium-ion battery is regarded as the next generation battery to replace the current commercial lithium-ion battery, with the advantages of abundant sodium resources, low price and high-level safety.
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