Lithium-based batteries are essential because of their increasing importance across several industries, particularly when it comes to electric vehicles and renewable energy storage. Sustainable batteries throughout their entire life cycle represent a key enabling technology for the zero pollution objectives of the European Green Deal.
Lithium metal batteries (LMBs) exhibit lower climate impact, lower abiotic depletion potential, and lower toxicity compared to similarly designed LIBs (NMC- and LFP-based). This is because the higher energy density in LMBs results in lower battery weight and electricity consumption in vehicles .
Additionally, the lithium iron phosphate battery (LFP) emerges as the best performer in the minerals and metals resource use category, boasting a 94 % reduction compared to lead-acid batteries. Consequently, LIBs prove to be superior to lead-acid batteries across various cradle-to-grave impact categories .
According to Table 1, there are different Li-based batteries, including Li-ion, Li-metal, Li-air, Li-polymer, and Li-S. Li-ion batteries are one of the most popular forms of energy storage commercialized due to their longer cycle life. Table 1. Main types and structures of Li-based rechargeable batteries.
The lithium-ion battery pack with NMC cathode and lithium metal anode (NMC-Li) is recognized as the most environmentally friendly new LIB based on 1 kWh storage capacity, with a cycle life approaching or surpassing lithium-ion battery pack with NMC cathode and graphite anode (NMC-C).
However, when considering different environmental impact metrics, electric vehicles equipped with LFP batteries are on par with or outperform those with Li-NMC batteries, a benefit linked to the lesser emissions from LFP battery materials and the predominant influence of vehicle manufacturing on these metrics.
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